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Gold Jewelry Information 4

Compounds
White Gold Gemstone BraceletAlthough gold is a noble metal, it forms many and diverse compounds. The oxidation state of gold in its compound ranges from -1 to 5+ but Au(I) and Au(III) dominate. Gold(I), referred to as the aurous ion, is the most common oxidation state with "soft" ligands such as thioethers, thiolates, and tertiary phosphines. Au(I) compounds are typically linear. A good example is Au(CN)2-, which is the soluble form of gold encountered in mining. Curiously, aurous complexes of water are rare. The binary gold halides, such as AuCl, form zig-zag polymeric chains, again featuring linear coordination at Au. Most drugs based on gold are Au(I) derivatives.

Gold(III) ("auric") is a common oxidation state and is illustrated by gold(III) chloride, AuCl3. Its derivative is chloroauric acid, HAuCl4, which forms when Au dissolves in aqua regia. Au(III) complexes, like other d8 compounds, are typically square planar.


Less common oxidation states: Au(-I), Au(II), and Au(V)
Compounds containing the Au- anion are called aurides. Caesium auride, CsAu which crystallizes in the caesium chloride motif. Other aurides include those of Rb+, K+, and tetramethylammonium (CH3)4N+.[14] Gold(II) compounds are usually diamagnetic with Au-Au bonds such as [Au(CH2)2P(C6H5)2]2Cl2. A noteworthy, legitimate Au(II) complex contains xenon as a ligand, [AuXe4](Sb2F11)2.[15] Gold pentafluoride is the sole example of Au(V), the highest verified oxidation state.[16]

Some gold compounds exhibit aurophilic bonding, which describes the tendency of gold ions to interact at distances that are too long to be a conventional Au-Au bond but shorter that van der Waals bonding. The interaction is estimated to be comparable in strength to that of a hydrogen bond.


Mixed valence compounds
Well-defined cluster compounds are numerous.[14] In such cases, gold has a fractional oxidation state. A representative example is the octahedral species {Au(P(C6H5)3)}62+. Gold chalcogenides, e.g. "AuS" feature equal amounts of Au(I) and Au(III).


Isotopes
There is one stable isotope of gold, and 18 radioisotopes with 195Au being the most stable with a half-life of 186 days.

Gold has been proposed as a "salting" material for nuclear weapons (cobalt is another, better-known salting material). A jacket of natural gold, irradiated by the intense high-energy neutron flux from an exploding thermonuclear weapon, would transmute into the radioactive isotope Au-198 with a half-life of 2.697 days and produce approximately .411 MeV of gamma radiation, significantly increasing the radioactivity of the weapon's fallout for several days. Such a weapon is not known to have ever been built, tested, or used.


Yellow Gold NecklaceSymbolism
Gold has been associated with the extremities of utmost evil and great sanctity throughout history. In the Book of Exodus, the Golden Calf is a symbol of idolatry and rebellion against God. In Communist propaganda, the golden pocket watch and its fastening golden chain were the characteristic accessories of the class enemy, the bourgeois and the industrial tycoons. Credit card companies associate their product with wealth by naming and coloring their top-of-the-range cards "gold;" although, in an attempt to out-do each other, platinum (and the even-more-elite black card) has now overtaken gold.

On the other hand in the Book of Genesis, Abraham was said to be rich in gold and silver, and Moses was instructed to cover the Mercy Seat of the Ark of the Covenant with pure gold. Eminent orators such as John Chrysostom were said to have a "mouth of gold with a silver tongue." Gold is associated with notable anniversaries, particularly in a 50-year cycle, such as a golden wedding anniversary, golden jubilee, etc.

Great human achievements are frequently rewarded with gold, in the form of medals and decorations. Winners of races and prizes are usually awarded the gold medal (such as the Olympic Games and the Nobel Prize), while many award statues are depicted in gold (such as the Academy Awards, the Golden Globe Awards the Emmy Awards, the Palme d'Or, and the British Academy Film Awards).

Medieval kings were inaugurated under the signs of sacred oil and a golden crown, the latter symbolizing the eternal shining light of heaven and thus a Christian king's divinely inspired authority. Wedding rings are traditionally made of gold; since it is long-lasting and unaffected by the passage of time, it is considered a suitable material for everyday wear as well as a metaphor for the relationship. In Orthodox Christianity, the wedded couple is adorned with a golden crown during the ceremony, an amalgamation of symbolic rites.

The symbolic value of gold varies greatly around the world, even within geographic regions. For example, gold is quite common in Turkey but considered a most valuable gift in Sicily.

From most ancient times, gold has been connected to religion and spirituality, especially associated with the Sun. It was also seen as the best material to decorate religious imagery, all over history.

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